Bu'aan kutaa 12ffaa ba'eera; bu'aa kee eessatti akka ilaaltu

Yaadannoo boqonnaa fi gaaffii shaakalaa

Boqonnaa 1 Keemistirii kutaa 12: Wal-madaallii Eesidii fi Beezii

Wanti fuula kana irra jiru hundi boqonnaa 1 kitaaba Keemistirii kutaa 12 tiif: wanta boqonnaan haguugu, yaadannoo gabaabaa, gaaffii shaakalaa deebii isaanii waliin, fi viidiyoo barnootaa bakka jirutti.

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4
Kaardii
10
Gaaffii shaakalaa boqonnaa 1
3–56
Fuula kitaabaa boqonnaa 1

Boqonnaan 1 maal haguuga

  1. 1.Acid-Base Concepts
  2. 2.Arrhenius Concept of Acids and Bases
  3. 3.Brønsted-Lowry Concept of Acids and Bases
  4. 4.Lewis Concept of Acids and Bases
  5. 5.Ionic Equlibria of Week Acids and Bases
  6. 6.Ionization of Water
  7. 7.Measures of the Strength of acids and Bases in Aque
  8. 8.Common Ion Effect and Buffer Solution
  9. 9.The Common Ion Effect
  10. 10.Buffer Solutions
  11. 11.Hydrolysis of Salts
  12. 12.Hydrolysis of Salts of Strong Acids and Strong Bases
  13. 13.Hydrolysis of Salts of Weak Acids and Strong Bases
  14. 14.Hydrolysis of Salts of Strong Acids and Weak Bases
  15. 15.Hydrolysis of Salts of Weak Acids and Week Bases
  16. 16.Acid-Base Indicators and Titrations
  17. 17.Acid-Base Indicators
  18. 18.Equivalents of Acids and Bases
  19. 19.Acid-Base Titrations

Yaadannoo gabaabaa boqonnaa 1

Kaardiiwwan fuula Keemistirii kutaa 12 irratti boqonnaa kana jala galmaa'an. Tokko tokkoon bani.

pH=pKa+log⁡([A−][HA])\text{pH} = \text{p}K_a + \log\left(\frac{[\text{A}^-]}{[\text{HA}]}\right)
pH\text{pH}
pH furmaata baafariidimensionlessdimensionless
pKa\text{p}K_a
logaritmii negaatiivii kan acid dissociation constantdimensionlessdimensionless
[A−][\text{A}^-]
molar concentration kan conjugate basemol L−1\text{mol}\,\text{L}^{-1}
[HA][\text{HA}]
molar concentration kan weak acidmol L−1\text{mol}\,\text{L}^{-1}

Yoom akka itti fayyadamtu

pH furmaata baafarii kan weak acid fi conjugate base irraa tolfame shallaguuf fayyadamaa.

Of eeggadhu

Reeshoo logaritmii keessatti concentration conjugate base lakkooftuu fi weak acid gedaantoo ta'uu qaba.

Grade 12 Chemistry, fuula 3-56 irraa qophaa'e; osoo hin ba'in dura yeroo lama mirkanaa'e

Kw=[H3O+][OH−]=1.0×10−14K_w = [\text{H}_3\text{O}^+][\text{OH}^-] = 1.0 \times 10^{-14}
KwK_w
dhaabbataa ion product bishaanii 25 °C irrattimol2 L−2\text{mol}^2\,\text{L}^{-2}
[H3O+][\text{H}_3\text{O}^+]
concentration kan hydronium ionmol L−1\text{mol}\,\text{L}^{-1}
[OH−][\text{OH}^-]
concentration kan hydroxide ionmol L−1\text{mol}\,\text{L}^{-1}

Yoom akka itti fayyadamtu

Concentration hydronium fi hydroxide walitti jijjiiruuf ykn 25 °C irratti pH fi pOH shallaguuf fayyadamaa.

Of eeggadhu

Gatiin 1.0 baay'isuu 10^-14 kan hojjatu 25 °C qofa irratti, teempireecheraan walqabatee ni jijjiirama.

Grade 12 Chemistry, fuula 3-56 irraa qophaa'e; osoo hin ba'in dura yeroo lama mirkanaa'e

Yoom akka itti fayyadamtu

Hisaaba walgitiinsa weak acids fi weak bases yeroo x concentration jalqabaa irraa hir'isuun salphistan.

Of eeggadhu

Gatiin x concentration jalqabaa irraa parsantii 5 ol yoo ta'e tilmaamni sun hin hojjatu, formula quadratic fayyadamuun dirqama.

Grade 12 Chemistry, fuula 3-56 irraa qophaa'e; osoo hin ba'in dura yeroo lama mirkanaa'e

Parent AcidParent BaseAmala FurmaataaHangi pH 25 °C irratti
StrongStrongNeutralpH=7\text{pH} = 7
WeakStrongBasicpH>7\text{pH} > 7
StrongWeakAcidicpH<7\text{pH} < 7
WeakWeakDepends on KaK_a and KbK_bKa>Kb⇒pH<7K_a > K_b \Rightarrow \text{pH} < 7

Yoom akka itti fayyadamtu

Furmaanni soogidda bishaan keessa baqe acidic, basic ykn neutral ta'uu isaa tilmaamuuf fayyadamaa.

Of eeggadhu

Soogidda weak acid fi weak base irraa dhufeef amala murteessuuf Ka kan cation fi Kb kan anion walbira qabuun barbaachisaadha.

Grade 12 Chemistry, fuula 3-56 irraa qophaa'e; osoo hin ba'in dura yeroo lama mirkanaa'e

Gaaffii shaakalaa boqonnaa 1

Gaaffii filannoo 10 boqonnaa kana irratti barreeffaman, tokkoon tokkoon isaanii deebii fi sababa qabu. Deebii banuu dura yaali. Gaaffiin kun Ingiliffaa tiin.

Gaaffii 1

Under the Brønsted Lowry concept, an acid is a substance that

  1. A.donates a proton
  2. B.accepts a proton
  3. C.accepts an electron pair
  4. D.produces hydroxide ions in water
Deebii fi sababa agarsiisi

Deebii: A donates a proton

Sababa

Brønsted Lowry defines an acid as a proton donor and a base as a proton acceptor. Option C is the Lewis definition of an acid and option D is the Arrhenius definition of a base.

Gaaffii 2

What is the conjugate base of H₂SO₄?

  1. A.SO₄²⁻
  2. B.HSO₄⁻
  3. C.H₃SO₄⁺
  4. D.H₂SO₃
Deebii fi sababa agarsiisi

Deebii: B HSO₄⁻

Sababa

A conjugate pair differs by exactly one proton. Removing one H⁺ from H₂SO₄ leaves HSO₄⁻. Option A is the conjugate base of HSO₄⁻, so it is two protons away and one step too far. Option C is the conjugate acid.

Gaaffii 3

What is the pH of a 0.001 mol/L solution of HCl?

  1. A.1
  2. B.2
  3. C.3
  4. D.11
Deebii fi sababa agarsiisi

Deebii: C 3

Sababa

HCl is a strong acid and ionizes completely, so the hydrogen ion concentration is 0.001, which is 10⁻³. pH is the negative logarithm of that, so pH = 3. Option D is the pOH, and pH plus pOH equals 14.

Gaaffii 4

BF₃ has no proton to give, yet it is classed as an acid. Under which concept, and why?

  1. A.Arrhenius, because it releases hydrogen ions
  2. B.Brønsted Lowry, because it donates a proton
  3. C.Lewis, because it accepts a pair of electrons
  4. D.It cannot be classed as an acid at all
Deebii fi sababa agarsiisi

Deebii: C Lewis, because it accepts a pair of electrons

Sababa

Boron in BF₃ has only six electrons around it, so it readily accepts an electron pair. That is the Lewis definition of an acid, and it is exactly why the Lewis concept is the broadest of the three.

Gaaffii 5

The Ka of a weak acid is 2.0 x 10⁻⁵. What is the Kb of its conjugate base?

  1. A.2.0 x 10⁻⁹
  2. B.5.0 x 10⁻¹⁰
  3. C.2.0 x 10⁻¹⁹
  4. D.5.0 x 10⁻⁵
Deebii fi sababa agarsiisi

Deebii: B 5.0 x 10⁻¹⁰

Sababa

For a conjugate pair, Ka multiplied by Kb equals Kw. So Kb = 1.0 x 10⁻¹⁴ divided by 2.0 x 10⁻⁵ = 5.0 x 10⁻¹⁰. Option C comes from multiplying the two values instead of dividing.

Gaaffii 6

A buffer contains a weak acid and its salt at equal concentrations. Its pH is

  1. A.7, because the two cancel out
  2. B.equal to the pKa of the acid
  3. C.equal to the pKb of the salt
  4. D.impossible to work out without the volumes
Deebii fi sababa agarsiisi

Deebii: B equal to the pKa of the acid

Sababa

The Henderson Hasselbalch equation gives pH = pKa + log([salt]/[acid]). When the two concentrations are equal the ratio is 1 and log 1 is zero, so pH equals pKa. This is also the point at which the buffer resists change most effectively.

Gaaffii 7

An aqueous solution of ammonium chloride is

  1. A.acidic, because the ammonium ion hydrolyses
  2. B.basic, because the chloride ion hydrolyses
  3. C.neutral, because it is a salt
  4. D.basic, because ammonia is a base
Deebii fi sababa agarsiisi

Deebii: A acidic, because the ammonium ion hydrolyses

Sababa

Ammonium chloride comes from a strong acid, HCl, and a weak base, ammonia. The stronger parent decides, so the solution is acidic. The ammonium ion reacts with water and releases hydronium ions, while the chloride ion is too weak a base to do anything.

Gaaffii 8

Which indicator is most suitable for titrating acetic acid with sodium hydroxide?

  1. A.Methyl orange
  2. B.Phenolphthalein
  3. C.Litmus
  4. D.Any of them works equally well
Deebii fi sababa agarsiisi

Deebii: B Phenolphthalein

Sababa

A weak acid with a strong base has its equivalence point above pH 7, because the salt formed hydrolyses to give a basic solution. Phenolphthalein changes between pH 8.3 and 10.0, which sits inside the steep part of that curve. Methyl orange would change far too early.

Gaaffii 9

Adding sodium acetate to a solution of acetic acid causes the ionization of the acid to decrease. This is

  1. A.the common ion effect
  2. B.hydrolysis
  3. C.neutralization
  4. D.titration
Deebii fi sababa agarsiisi

Deebii: A the common ion effect

Sababa

Sodium acetate supplies acetate ions, which the acid already produces. By Le Chatelier's principle the extra acetate pushes the ionization equilibrium back to the left, so fewer hydronium ions form. That suppression is the common ion effect, and it is the basis of how a buffer is made.

Gaaffii 10

Water at 50 degrees Celsius has a pH slightly below 7. What does this tell you?

  1. A.The water has become acidic
  2. B.The water is still neutral, because Kw rises with temperature
  3. C.The measurement must be wrong
  4. D.The water has dissolved carbon dioxide
Deebii fi sababa agarsiisi

Deebii: B The water is still neutral, because Kw rises with temperature

Sababa

Neutral means the hydronium and hydroxide concentrations are equal, not that the pH reads exactly 7. Kw increases with temperature, so both concentrations rise and the neutral pH falls below 7 while remaining neutral. The value 7 only applies at 25 degrees Celsius.

Appiin boqonnaa kana irratti gaaffii 12 qaba; utuu hojjettuu ni sirreessa. Kan asii jiran 10 jalqabaa ti.

Fuula kitaabaa boqonnaa 1

Boqonnaan 1 Maxxansa Ministeera Barnootaa keessatti fuula 3 hanga fuula 56 ti.

Maxxansa Ministeera Barnootaa, Ingiliffaa, Fuula 298

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